Lithiation of 3',5'-O-(tetraisopropyldisiloxane-1,3-diyl)-2'-deoxyuridine: synthesis of 6-substituted 2'-deoxyuridines

DOI: 10.1016/S0040-4020(01)96402-6

Source and publish data:

Tetrahedron p. 861 - 866 (1985)

Update date:2022-07-29

Topics: Synthesis Lithiation 6-substituted

Authors:

Tanaka, Hiromichi

Hayakawa, Hiroyuki

Iijima, Shuji

Haraguchi, Kazuhiro

Miyasaka, Tadashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)96402-6

Synthesis of 6-substituted 2'-deoxyuridines can be effected by lithiation of 3',5'-O-(tetraisopropyldisiloxane-1,3-diyl)-2'-deoxyuridine with LDA followed by the reaction of its lithio derivative with electrophiles. This method provides a general, regiosp

Full text of DOI:10.1016/S0040-4020(01)96402-6

Products guided by the article

Product name:6-phenylhydroxymethyl-2'-deoxyuridine

Cas No:98495-68-2

R&D Labs maybe for 98495-68-2

Shanghai Pinewood Fine Chemical Co., Ltd.

website:http://www.pinewoodchem.com

Contact:0086-21-62417129，62414096

Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Yueyang Hudex Pharmaceuticals Ltd.

Contact:0730-8748800

Address:Wujiang Bridge，Yueyang Economy & Technology Development Zone
Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
jiangsu hualin chemical co.,ltd.

Contact:86-25-87787402

Address:jaingsu,china

Relevant to this article

Tuning diketodioxinone reactivity: Biomimetic synthesis of the resorcylate antibiotic fungal metabolites ent-W1278A, -B, and -C, using iterative aromatization reactions

Doi:10.1021/jo9015858
(2009)
Synthesis of substituted benz[g]indole-6,9-diones and benzo[h]quinoline-7, 10-diones by heterocyclization of 6-alkynyl-5-amino-1,4-naphthoquinones

Doi:10.1007/s11172-005-0266-8
(2005)
One-electron Oxidation of Closed-shell Molecules. Part 3. Oxidative Cleavage of 1,2,2,2-Tetrakis-(p-methoxyphenyl)ethanone with Dibenzoyl and Bis(3,5-dinitrobenzoyl) Peroxides: Mechanistic Changeover of the Peroxide Function from Radical to Molecular Oxidation

Doi:10.1039/P29830001301
(1983)
A New Synthesis of o-Prenyl Phenols

Doi:10.1039/c39830000738
(1983)
A simple and facile stereoselective synthesis of (Z)- and (E)-allyl halides catalyzed by silica supported sodium hydrogen sulfate: Factors influencing the yields and stereochemistry of allyl halides

Doi:10.1016/j.tet.2004.07.022
(2004)
(±)-4-Aryl-4,5-dihydro-3H-1,3-benzodiazepines. 3. 2-Phenyl and 2-amino analogues as potential antihypertensive agents

Doi:10.1021/jm00369a029
(1984)

Article Doi