Journal of the Chemical Society. Chemical communications p. 738 - 739 (1983)
Update date:2022-07-29
Topics:
Mohamed, Salah E. N.
Thomas, Philip
Whiting, Donald A.
Phenylthiyl radicals add regiospecifically to isoprenoid chrom-3-enes to yield 3-phenylthiochromans which open to o-prenylphenols on electron transfer from metal naphthalenides or a mercury cathode; the two-step process is tolerant of free phenol and carbonyl functions, and trisubstituted double bonds.
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