On the Mechanism of Reduction of Dithiocarbonates (Xanthates) with Tributylstannane

DOI: 10.1039/c39850000646

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 646 - 647 (1985)

Update date:2022-09-26

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Authors:

Barton, Derek H. R.

Crich, David

Loebberding, Antonius

Zard, Samir Z.

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Article abstract of DOI:10.1039/c39850000646

Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct S_H2 attack on sulphide sulphur.

Full text of DOI:10.1039/c39850000646

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