THE BEHAVIOR OF ALKOXIDES WITH ALLYL(CHLOROMETHYL)DIMETHYLSILANES AND (CHLOROMETHYL)DIMETHYLVINYLSILANE; THE ABILITIES OF ALLYL AND VINYL GROUPS TO MIGRATE FROM PENTACOORDINATE SILICON

Article abstract of DOI:10.1016/S0040-4039(00)98411-9

Sodium methoxide in tetrahydrofuran attacks silicon in allyl(chloromethyl)-dimethylsilane and in (chloromethyl)dimethylvinylsilane with displacement of chloride and 1,2-migration of the allyl and the vinyl groups to give 1-(3-butenyl)methoxydimethylsilane and allylmethoxydimethylsilane.