THE BEHAVIOR OF ALKOXIDES WITH ALLYL(CHLOROMETHYL)DIMETHYLSILANES AND (CHLOROMETHYL)DIMETHYLVINYLSILANE; THE ABILITIES OF ALLYL AND VINYL GROUPS TO MIGRATE FROM PENTACOORDINATE SILICON

DOI: 10.1016/S0040-4039(00)98411-9

Source and publish data:

Tetrahedron Letters p. 1119 - 1122 (1985)

Update date:2022-09-26

Topics:

Authors:

Sans, E. A.

Shechter, H.

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Article abstract of DOI:10.1016/S0040-4039(00)98411-9

Sodium methoxide in tetrahydrofuran attacks silicon in allyl(chloromethyl)-dimethylsilane and in (chloromethyl)dimethylvinylsilane with displacement of chloride and 1,2-migration of the allyl and the vinyl groups to give 1-(3-butenyl)methoxydimethylsilane and allylmethoxydimethylsilane.

Full text of DOI:10.1016/S0040-4039(00)98411-9

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