Practical Synthesis of β-D-Xyl-(1->2)-β-D-Man-(1->4)-α-D-Glc-OMe, a Trisaccharide Component of the Hyriopsis schlegelii Glycosphingolipid

Article abstract of DOI:10.1021/jo00101a036

By employing the readily accessible (preceding paper in this issue) 3,4,6-tri-O-benzyl-α-D-arabino-hexosyl bromide (1) as an indirect, β-specific mannosyl donor, a practical three-step synthesis was elaborated for methyl xylosyl-β(1->2)-mannosyl-β(1->4)-g