Chemistry Letters p. 1169 - 1172 (1992)
Update date:2022-08-04
Topics:
Gu, Jin-Hua
Okamoto, Mikako
Terada, Masahiro
Mikami, Koichi
Nakai, Takeshi
The Eu(III)-catalyzed cyanosilylations of chiral α-alkoxy and α-amino aldehydes are shown to exhibit syn diastereofacial selection, the degree increasing with an increase in steric bulk of the alkyl chain in the aldehydes.The mechanism of this catalytic p
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