Reactions of β-Azidostyrenes with Halogenoacetic Acid. A novel Formation of Oxazoles

DOI: 10.1039/c39890001414

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Journal of the Chemical Society. Chemical communications p. 1414 - 1415 (1989)

Update date:2022-08-03

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Authors:

Takeuchi, Hiroshi

Kitamura, Yasunori

Hayakawa, Satoshi

Koyama, Kikuhiko

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Article abstract of DOI:10.1039/c39890001414

The reaction of β.azidostyrene with trifluoro-, trichloro-, or monochloro-acetic acid gave 2-halogenomethyl-5-phenyloxazole via attack of halogenoacetate anion on a benzylic carbocation or a conjugate acid of the azide.

Full text of DOI:10.1039/c39890001414

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