Mechanism of Cyclopentene-1-carboxaldehyde Formation by Ring Contraction of 2,3-Epoxycyclohexanols. Improved Synthetic Procedures

DOI: 10.1021/jo00352a015

Source and publish data:

Journal of Organic Chemistry p. 212 - 217 (1986)

Update date:2022-09-26

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Authors:

Bergman, Rolf

Magnusson, Goeran

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Article abstract of DOI:10.1021/jo00352a015

Complete analysis of the reaction mixtures from lithium bromide induced skeletal rearrangement of cis- and trans-1-deuterio-4,4-dimethyl-2,3-epoxycyclohexanol (4d and 7d) showed that the formation of specifically deuterated 5,5- and 3,3-dimethylcyclopente

Full text of DOI:10.1021/jo00352a015

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