Mechanism of Cyclopentene-1-carboxaldehyde Formation by Ring Contraction of 2,3-Epoxycyclohexanols. Improved Synthetic Procedures

DOI: 10.1021/jo00352a015

Source and publish data:

Journal of Organic Chemistry p. 212 - 217 (1986)

Update date:2022-09-26

Topics:

Authors:

Bergman, Rolf

Magnusson, Goeran

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00352a015

Complete analysis of the reaction mixtures from lithium bromide induced skeletal rearrangement of cis- and trans-1-deuterio-4,4-dimethyl-2,3-epoxycyclohexanol (4d and 7d) showed that the formation of specifically deuterated 5,5- and 3,3-dimethylcyclopente

Full text of DOI:10.1021/jo00352a015

Products guided by the article

Product name:1-deuterio-4,4-dimethylcyclohex-2-enol

Cas No:99342-63-9

R&D Labs maybe for 99342-63-9

Triumph International Development Limilted

website:http://www.jiashengchem.cn/

Contact:+86-536-7971999

Address:Yinhai Road,Shouguang
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
Wuxi Forest Biological Co.,Ltd

Contact:+86-510-81602300

Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
HANGZHOU YUNUO CHEMICAL CO.,LTD

website:http://www.yunuochem.com

Contact:0571-83715115

Address:hangzhou
Nanyang Tianhua pharmaceutical Co.,Ltd.

Contact:+8618639816203

Address:Longsheng Industrial Park

Relevant to this article

A Convenient Synthesis of 3-Acylindoles via Friedel-Crafts Acylation of 1-(Phenylsulfonyl)indole. A New Route to Pyridocarbazole-5,11-quinones and Ellipticine

Doi:10.1021/jo00350a001
(1985)
A one-pot esterification of chiral O-trimethylsilyl-cyanohydrins with retention of stereochemistry

Doi:10.1016/S0040-4039(02)01200-5
(2002)
Deuterium Kinetic Isotope Effects in the 1,4-Dimethylenecyclohexane Boat Cope Rearrangement

Doi:10.1021/ja00263a017
(1986)
Doi:10.1021/ja01359a044
(1931)
A synthetic approach to (+)-aldosterone and its relatives (2)-. A stereoselective synthesis of (+)-trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)hydri ndane

Doi:10.1016/S0040-4020(01)96631-1
(1985)
Synthesis of 2,3-Disubstituted Indoles via Claisen Ortho Ester Rearrangement: An Approach for the Synthesis of Vindrosine

Doi:10.1021/jo00352a001
(1986)

Article Doi