Mechanism of Cyclopentene-1-carboxaldehyde Formation by Ring Contraction of 2,3-Epoxycyclohexanols. Improved Synthetic Procedures

DOI: 10.1021/jo00352a015

Source and publish data:

Journal of Organic Chemistry p. 212 - 217 (1986)

Update date:2022-09-26

Topics:

Authors:

Bergman, Rolf

Magnusson, Goeran

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00352a015

Complete analysis of the reaction mixtures from lithium bromide induced skeletal rearrangement of cis- and trans-1-deuterio-4,4-dimethyl-2,3-epoxycyclohexanol (4d and 7d) showed that the formation of specifically deuterated 5,5- and 3,3-dimethylcyclopente

Full text of DOI:10.1021/jo00352a015

Products guided by the article

Product name:1-deuterio-4,4-dimethylcyclohex-2-enol

Cas No:99342-63-9

R&D Labs maybe for 99342-63-9

Jinan Aery Pharmaceutical Co,.Ltd

Contact:+8653181263406

Address:1-1916,Building1 Fenghuang SOHO,Fenghuang Road,High-tech Zone,Jinan,Shandong
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Chengdu Gelipu Biotechnology Co., Ltd.

website:http://www.glp-china.com

Contact:86-28-82610909

Address:chegndu
Hubei Lansun Biochemical Pharmaceutical Co., Ltd

Contact:714-6395977

Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China
Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park

Relevant to this article

A Convenient Synthesis of 3-Acylindoles via Friedel-Crafts Acylation of 1-(Phenylsulfonyl)indole. A New Route to Pyridocarbazole-5,11-quinones and Ellipticine

Doi:10.1021/jo00350a001
(1985)
A one-pot esterification of chiral O-trimethylsilyl-cyanohydrins with retention of stereochemistry

Doi:10.1016/S0040-4039(02)01200-5
(2002)
Deuterium Kinetic Isotope Effects in the 1,4-Dimethylenecyclohexane Boat Cope Rearrangement

Doi:10.1021/ja00263a017
(1986)
Doi:10.1021/ja01359a044
(1931)
A synthetic approach to (+)-aldosterone and its relatives (2)-. A stereoselective synthesis of (+)-trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)hydri ndane

Doi:10.1016/S0040-4020(01)96631-1
(1985)
Synthesis of 2,3-Disubstituted Indoles via Claisen Ortho Ester Rearrangement: An Approach for the Synthesis of Vindrosine

Doi:10.1021/jo00352a001
(1986)

Article Doi