Tetrahedron Letters p. 2649 - 2652 (1985)
Update date:2022-08-04
Topics:
Dunach, E.
Kagan, H. B.
(R)-(-)-N-(3,5-dinitrobenzoyl)-α-phenylethylamine is a chiral shift reagent which allows ee measurements of various phosphine oxides.Good results were obtained for monophosphine oxides with asymmetric phosphorus centers as well as with an asymmetric carbon in α position of phosphorus.The reagent is also able differentiate the two enantiomers of racemic DIOP dioxide.
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Doi:10.1002/anie.202017086
(2021)Doi:10.1021/jo00350a073
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(2017)
