Chemical Communications p. 7163 - 7166 (2018)
Update date:2022-08-04
Topics:
Mai, Juri
Arkhypchuk, Anna I.
Gupta, Arvind Kumar
Ott, Sascha
Stilbenes with push-pull electronics are directly accessible from an electron-rich and an electron-deficient benzaldehyde in a novel reductive aldehyde cross-coupling reaction. The one-pot procedure is enabled by the oxidation of a transient phosphinite to the corresponding phosphinate which exhibits sufficient reactivity towards deactivated aldehydes.
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