
Journal of the Chemical Society, Dalton Transactions p. 1361 - 1364 (1985)
Update date:2022-08-04
Topics:
Alcock, Nathaniel W.
Curzon, Eirian H.
Moore, Peter
Omar, Hadi, A. A.
Pierpoint, Colin
Two new pendant-arm sixteen-membered ring penta-aza macrocycles, 1-(2'-dimethylaminoethyl)-1,5,9,13-tetra-azacyclohexadecane (L1) and 1-(2'-dimethylaminoethyl)-5,9,13-trimethyl-1,5,9,13-tetra-azacyclohexadecane (L2) have been prepared and the complexes of L1 with Ni2+, Cu2+, Co2+, Zn2+, Cd2+, and Hg2+, investigated.The ions Ni2+, Cu2+, and Co2+ form high-spin five-co-ordinnate complexes.Carbon-13 n.m.r. spectroscopy shows
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