Journal of Organic Chemistry p. 5747 - 5753 (1985)
Update date:2022-08-04
Topics: Precursor Sesquiterpene Lactones Experimental Furanose Controlled access
Georges, Michael
Tam, Tim-Fat
Fraser-Reid, Bert
The diester 4a which is readily obtained from "diacetone glucose" (1) undergoes Dieckmann cyclization to give the two possible β-keto esters, 5 and 6, in a ratio of 8:1.The carbonyl and esters groups on the cyclohexane ring of the major isomer are process
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(1957)Doi:10.1016/j.bmc.2008.01.036
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(1985)