Isolation of η2-(C,C) Ketene Complexes of Nickel from the Reactions of Nickelacyclobutane Complexes with Carbon Monoxide

DOI: 10.1039/c39850000850

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Journal of the Chemical Society. Chemical communications p. 850 - 851 (1985)

Update date:2022-08-04

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Authors:

Miyashita, Akira

Shitara, Hiroaki

Nohira, Hiroyuki

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Article abstract of DOI:10.1039/c39850000850

The η²-(C,C) ketene complex , a model complex for homogeneous CO reduction, was isolated by carbonylation of nickelacyclobutane complexes or by the reaction of with CH2Br2 in the presence of Zn followed by carbonylation.

Full text of DOI:10.1039/c39850000850

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