Contribution of methyls in retinal side chain to regioselective photoisomerization of retinochromes

DOI: 10.1246/cl.1999.1051

Source and publish data:

Chemistry Letters p. 1051 - 1052 (1999)

Update date:2022-08-04

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Authors:

Tsujimoto, Kazuo

Sugiura, Jun'ichirou

Takemori, Nobuaki

Mizukami, Taku

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Article abstract of DOI:10.1246/cl.1999.1051

All-trans-9-demethyl-11-methylretinal was synthesized to elucidate the chromophoric interaction between hydrophobic part in retinochrome and 9-methyl substituent of retinal. Photoirradiation of its pigment efficiently gave the 11-cis-isomer in 90% regiose

Full text of DOI:10.1246/cl.1999.1051

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