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"Naked" Hydrogencarbonate Ion as a Bifunctional Catalyst toward Amide Substrates. Nucleophilic Ion Pairs. 9.

DOI: 10.1246/bcsj.54.840

Source and publish data:

Bulletin of the Chemical Society of Japan p. 840 - 845 (1981)

Update date:2022-08-30

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Authors:

Shinkai, SeijiShinkai, Seiji

Nakashima, NaotoshiNakashima, Naotoshi

Kunitake, ToyokiKunitake, Toyoki

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Article abstract of DOI:10.1246/bcsj.54.840

The cleavage of amide substrates(p-nitro-N-methyltrifluoroacetanilide and p-nitro-N-methyldichloroacetanilide) with anionic nucleophiles was studied at 30 deg C in aprotic (acetonitrile and N,N-dimethylformamide) and protic (ethanol) media.Hydrogencarbona

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Full text of DOI:10.1246/bcsj.54.840

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