Novel change in rate-determining step within an E1cB mechanism during aminolysis of a sulfamate ester in acetonitrile

DOI: 10.1039/a801505h

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Chemical Communications p. 1017 - 1018 (1998)

Update date:2022-08-11

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Authors:

Spillane, William J.

McGrath, Paul

Brack, Chris

Barry, Keith

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Article abstract of DOI:10.1039/a801505h

The observation of biphasic Bronsted plots (β₁ ca. 0.7 and β₂ ca. 0) in the aminolysis (alicyclic amines, pyridines) of 4-nitrophenyl N-benzylsulfamate 1a in MeCN is interpreted as being due to a mechanistic change from (ElcB)_ir

Full text of DOI:10.1039/a801505h

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Article Doi

Novel change in rate-determining step within an E1cB mechanism during aminolysis of a sulfamate ester in acetonitrile

DOI: 10.1039/a801505h

Source and publish data:

Authors:

Article abstract of DOI:10.1039/a801505h

Full text of DOI:10.1039/a801505h

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