Tetrahedron Letters p. 1047 - 1050 (1994)
Update date:2022-08-11
Topics:
Fuerstner, Alois
Singer, Robert
Knochel, Paul
Aryl- and hetero-aryl iodides react under very mild conditions (THF, 25 deg C) with a Zn(Ag) couple deposited on graphite leading to the corresponding zinc reagents in excellent yields.In the presence of CuCN*2LiCl or catalytic amounts of Pd(O), these unsaturated zinc species can be acylated, allylated or coupled with iodoalkenes.
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