Journal of the Chemical Society. Chemical communications p. 870 - 871 (1987)
Update date:2022-08-30
Topics:
Moodie, Roy B.
Richards, Stuart N.
Thorne, Melanie P.
The oxidation of 2-phenylpropan-2-ol to acetophenone by nitrous acid in aqueous sulphuric acid takes place following rate-determining dehydration to α-methylstyrene, and the nitrous acid oxidation of 1-arylethanols consists of two competing reactions which are α-hydride abstraction by nitrosonium ion to give the acetophenone and dehydration followed by oxidation of the styrene to give the benzaldehyde.
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