
Tetrahedron p. 5971 - 5978 (1989)
Update date:2022-08-30
Topics:
Cardinale, G.
Grimmelikhuysen, J. C.
Laan, J. A. M.
Lier, F. P. van
Steen, D. van der
Ward, J. P.
A synthesis is described of alkyl chlorides by reaction of methoxy hydroperoxides, prepared from 1-alkenes by ozonisation in methanol, with ferric chloride: RCH=CH2 --> RCH(OOH)OCH3 --> R. --> RCl.Yields of 1-chlorotetradecane were about 60percent; those of other halides from 38 to 57percent.
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