Simple anf Efficient Palladium-Catalyzed Carbonylation of Iodoxyarenes in Water under Mild Conditions

DOI: 10.1021/jo00070a008

Source and publish data:

Journal of Organic Chemistry p. 4794 - 4795 (1993)

Update date:2022-08-11

Topics:

Authors:

Grushin, Vladimir V.

Alper, Hovard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00070a008

Iodoxyarenes (ArIO2) readily react with CO (1 atm) in water, in the presence of Na2 (0.1percent) and Na2CO3 at 40-50 deg C, to give the corresponding carboxylic acids, ArCOOH, in 55-89percent isolated yield.Particulary attractive features of the reaction are that, unlike most iodoarenes, ArIO2 can be carbonylated in aqueous media without any organic solvents, due to their solubility in water and high reactivity.

Full text of DOI:10.1021/jo00070a008

Products guided by the article

Product name:Anisic acid

Cas No:100-09-4

R&D Labs maybe for 100-09-4

Xi'an caijing Opto-Electrical Science & Technology Co., LTD

Contact:+86-29-88294447

Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Guangzhou Swan Chemical Co., Ltd.

Contact:+86-20-31075659

Address:NO.301, Hong ba fang investment BLDG 1,Guan chong village,Shiqi town,Panyu district,Guangzhou
Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China

Relevant to this article

Electrocatalytic dehydrochlorination of pentachlorophenol to phenol or cyclohexanol

Doi:10.1021/es9911465
(2000)
Vanadium(II) complexes as efficient reagents for direct construction of asymmetric quaternary carbons from carbonyl compounds

Doi:10.1016/0040-4039(95)01299-W
(1995)
Catalytic Carbonylative Spirolactonization of Hydroxycyclopropanols

Doi:10.1021/jacs.6b06573
(2016)
Doi:10.1021/jo01214a011
(1939)
The influence of the organolithium reagent nature on the possibility of the O→C_sp migration of the R₃Si group in propynes HC≡CCH₂OSiR₃

Doi:10.1007/s11172-017-2012-4
(2017)
Synthesis of β-Substituted γ-Aminobutyric Acid Derivatives through Enantioselective Photoredox Catalysis

Doi:10.1002/anie.201804040
(2018)

Article Doi