A Novel Fragmentation Reaction of α-(N-Siloxy)anilino Ketones induced by Fluoride Ions

DOI: 10.1039/c39880001530

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1530 - 1531 (1988)

Update date:2022-08-11

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Authors:

Ohno, Masatomi

Ido, Motohisa

Eguchi, Shoji

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Article abstract of DOI:10.1039/c39880001530

The reaction of α-(N-siloxy)anilino-substituted aromatic ketones with tetrabutylammonium fluoride afforded aromatic acids and aniline as the fragmentation products, presumably via ring rupture of the intermediate 1,2-oxazetidine.

Full text of DOI:10.1039/c39880001530

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