Journal of the American Chemical Society
Article
Chunhua Hu for his assistance with the single crystal data
collection and structure determination.
Table 3. Substrate Scope for the Tandem Reactions Using 6
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optimal microenvironments for each reaction and fast intra-
micellar diffusion of the intermediate. Our strategy should be
generalizable and paves the way for unforeseen tandem
reactions that involve incompatible catalytic transformations.
The number of catalytic steps that can be combined using this
strategy is currently limited by the number of functionalized
domains within a micelle. Future research in our group will
therefore address the preparation of multicompartment
micelles with more than two domains to compartmentalize
more sophisticated sequential catalytic reactions.
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ASSOCIATED CONTENT
* Supporting Information
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S
Chrystallographic data (CIF)
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AUTHOR INFORMATION
Corresponding Author
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(31) Chi, Y.; Scroggins, S. T.; Frec
130, 6322.
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het, J. M. J. J. Am. Chem. Soc. 2008,
Notes
The authors declare no competing financial interest.
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Nolte, R. J. M.; van Hest, J. C. M. Chem. - Eur. J. 2009, 15, 1107.
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ACKNOWLEDGMENTS
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Funding provided by the U.S. Department of Energy, Office of
Basic Energy Sciences, through Catalysis Science Contract DE-
FG02-03ER15459, is gratefully acknowledged. J.D. is thankful
to the Thomas-und-Ulla-Kolbeck-Stiftung for financial support.
We thank the NYU Molecular Design Institute for the purchase
of the Bruker SMART APEXII Diffractometer, and Dr.
(36) Liu, Y.; Wang, Y.; Wang, Y.; Lu, J.; Pinon, I.; Victor; Weck, M. J.
Am. Chem. Soc. 2011, 133, 14260.
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