EFFECTS OF METHANOL SOLVATION ON THE NUCLEOPHILIC REACTIONS OF THIOLATES WITH 2-SUBSTITUTED-2-NITROPROPANES

DOI: 10.1016/S0040-4039(00)99911-8

Source and publish data:

Tetrahedron Letters p. 461 - 464 (1984)

Update date:2022-08-17

Topics:

Authors:

Al-Khalil, Suleiman I.

Bowman, W. Russell

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Article abstract of DOI:10.1016/S0040-4039(00)99911-8

Methanol solvation prevents S_RN1 substitution in the reaction of Me2C(X)NO2 with thiolates and favours an alternative redox reaction to yield disulphide and nitronate.

Full text of DOI:10.1016/S0040-4039(00)99911-8

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