Selective Synthesis of Ethylbenzene and Styrene by Cross-coupling between Toluene and Methane over a Lithium-promoted Y2O3-CaO Catalyst

DOI: 10.1039/c39900001434

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Journal of the Chemical Society. Chemical communications p. 1434 - 1436 (1990)

Update date:2022-08-28

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Authors:

Osada, Yo

Ogasawara, Sadao

Fukushima, Takakazu

Shikada, Tsutomu

Ikariya, Takao

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Article abstract of DOI:10.1039/c39900001434

Isotope-labelling experiments have shown that toluene oxidative methylation using methane to form C8 hydrocarbons over a lithium-promoted Y2O3-CaO catalyst involves a cross-coupling between the methyl and benzyl radicals on the surface.

Full text of DOI:10.1039/c39900001434

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