Chemistry Letters p. 103 - 106 (1980)
Update date:2022-08-16
Topics:
Sato, Fumie
Tomuro, Yasuji
Ishikawa, Hiroaki
Oikawa, Takeshi
Various aluminum allyl and benzyl alkoxides and allyl ethers undergo hydrogenolysis by LiAlH4 in the presence of catalytic amount of TiCl4 or Cp2TiCl2.Thus, the present reaction provides a convenient method for replacing oxygen-containing functional groups at the allylic or benzylic position by hydrogen.
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