Chemistry Letters p. 449 - 452 (1989)
Update date:2022-08-11
Topics:
Mukaiyama, Teruaki
Isayama, Shigeru
Inoki, Satoshi
Kato, Koji
Yamada, Tohru
Takai, Toshihiro
In the presence of a catalytic amount of bis(acetylacetonato)cobalt(II), various olefins are hydrated with oxygen and secondary alcohol to afford the corresponding alcohols together with alkanes and ketones via Oxidation-Reduction process.Effect of additives in the present hydration reaction shows that 2,6-lutidine and 2-picoline inhibit the production of alkanes in a large extent to result in the better yielding of alcohols.
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