Tetrahedron Letters p. 9201 - 9204 (1998)
Update date:2022-08-29
Topics:
Terao, Jun
Watanabe, Tsunenori
Saito, Koyu
Kambe, Nobuaki
Sonoda, Noboru
Styrenes were alkylated with alkyl tosylates, sulfates and bromides in the presence of a zirconocene catalyst and (n)BuMgCl in THF. By the use of this reaction, primary and secondary alkyl groups can be introduced regioselectively at the benzylic carbon of styrenes to give α-substituted ethylbenzenes.
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