Tetrahedron Letters p. 2561 - 2564 (1996)
Update date:2022-08-11
Topics:
Soderquist, John A.
Vaquer, Jaime
Diaz, Michael J.
Rane, Anil M.
Bordwell, Frederick G.
Zhang, Shizhong
A new solid-liquid phase transfer catalyst, trisopropylsilanol (TIPSOH), has been developed which, through the silanol/silanoate system, allows KOH to quantitatively convert even primary alkyl halides to alkenes avoiding both ether and alcohol by-products. Its potential application in the detoxification of mustard gas analogues and environmental pollutants has been demonstrated.
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