Evidence for a 1,3-Sigmatropic Rearrangement of a Nitrile N-Benzylimide to a C-Benzyl-substituted Diazoalkane

DOI: 10.1039/c39800001229

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1229 - 1230 (1980)

Update date:2022-08-16

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Authors:

Padwa, Albert

Caruso, Thomas

Plache, David

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Article abstract of DOI:10.1039/c39800001229

The flash vacuum pyrolysis of N-benzyl-2-phenyl-1,3,4-oxadiazolin-5-one generates a nitrile N-imide which rearranges to a diazoalkane via a 1,3-sigmatropic benzyl shift.

Full text of DOI:10.1039/c39800001229

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