Evidence for a 1,3-Sigmatropic Rearrangement of a Nitrile N-Benzylimide to a C-Benzyl-substituted Diazoalkane

DOI: 10.1039/c39800001229

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1229 - 1230 (1980)

Update date:2022-08-16

Topics:

Authors:

Padwa, Albert

Caruso, Thomas

Plache, David

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800001229

The flash vacuum pyrolysis of N-benzyl-2-phenyl-1,3,4-oxadiazolin-5-one generates a nitrile N-imide which rearranges to a diazoalkane via a 1,3-sigmatropic benzyl shift.

Full text of DOI:10.1039/c39800001229

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzonitrile

Cas No:100-47-0

R&D Labs maybe for 100-47-0

Chemsigma International Co.,Ltd.

website:http://www.chemsigma.com

Contact:86-025-58748998

Address:Rm.705, 15th Building,Rd.Xinke II
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
Allright GC (Jinan) Biotechnology Ltd.

website:https://www.argcbiotech.com/

Contact:86-18405413579-

Address: No.27566 of Jingshiroad, Huaiyin District, Jinan City(250011), Shandong Province, China.
Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road

Relevant to this article

Improved, one-pot synthesis of 6-[¹⁸F]fluorodopamine and quality control testing for use in patients with neuroblastoma

Doi:10.1002/jlcr.3685
(2018)
ASYMMETRIC HYDROGENATION IN THE PRESENCE OF BISDIPHENYLPHOSPHINE COMPLEXES OF RHODIUM. 3. MOLECULAR STRUCTURE OF 2R-3-PHENYL-2-(N-METHYLDIPHENYLPHOSPHINAMINO)-1-DIPHENYLPHOSPHINOXYPROPANE(1,5-CYCLOOCTADIENE)RHODIUM(I) PERCHLORATE AND ITS EFFECTIVENESS AS AN ENANTIOSELECTIVE CATALYST

Doi:10.1007/BF00955817
(1987)
Pulse Radiolysis of Cycloserine in Aqueous Solutions. One-Electron Oxidation by OH Radicals

Doi:10.1246/bcsj.57.3403
(1984)
Electrochemical reduction of carbon dioxide with an electrode mediator and homogeneous catalysts

Doi:10.1016/0304-5102(89)80191-9
(1989)
Phosphine-free palladium(II)-catalyzed arylation of naphthalene and benzene with aryl iodides

Doi:10.1021/jo801345b
(2008)
New synthesis of isoquinoline derivatives by reactions of 2-(2-methoxyethenyl)benzonitriles with organolithiums and lithium dialkylamides

Doi:10.1246/cl.2004.236
(2004)

Article Doi