Tetrahedron Letters p. 8957 - 8960 (1994)
Update date:2022-08-16
Topics:
Soundararajan, Raman
Li, Guisheng
Brown, Herbert C.
A comparative study of the homologation of representative boronic esters with in situ generated LiCH2X (X = Cl; Br; I) is presented wherein the reactivity differences arising out of the steric and electronic effects of the migrating groups, and the nature of the ester groups are determined and discussed.
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