Bulletin of the Chemical Society of Japan p. 1195 - 1200 (1986)
Update date:2022-08-11
Topics:
Ishida, Akito
Yamashita, Shinya
Toki, Susumu
Takamuku, Setsuo
The photoirradiation of a methanol solution of EuCl3 and alkenes such as cyclohexene, cyclooctene, cyclododecene, and tetramethylene afforded (hydroxymethyl)alkane.The dihydro dimer of alkene,hydrogen, and ethylene glycol are also formed.Reactions proceed via a radical mechanism induced by hydrogen atoms and hydroxymethyl radicals, which are produced by a photoredoc reaction of EuIII/EuII in methanol.
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