Rhodium-Catalyzed C,C-Double Bond Cleavage by Molecular Oxygen

DOI: 10.1002/hlca.19830660119

Source and publish data:

Helvetica Chimica Acta p. 177 - 185 (1983)

Update date:2022-08-11

Topics:

Authors:

Boennemann, Helmut

Nunez, Washington

Rohe, Dieter M. M.

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Article abstract of DOI:10.1002/hlca.19830660119

Acetylacetonatorhodiumolefin systems, allylrhodium complexes, or (Ph3P)3RhCl catalyzed the conversion of alkenes and molecular oxygen to carbonyl compounds via C=C-bond cleavage.For example, 2,3-dimethyl-2-butene was transformed into acetone.Butadiene and isoprene also undergo oxidative C=C-bond cleavage to form acrylaldehyde and related compounds.

Full text of DOI:10.1002/hlca.19830660119

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