Rhodium-Catalyzed C,C-Double Bond Cleavage by Molecular Oxygen

DOI: 10.1002/hlca.19830660119

Source and publish data:

Helvetica Chimica Acta p. 177 - 185 (1983)

Update date:2022-08-11

Topics:

Authors:

Boennemann, Helmut

Nunez, Washington

Rohe, Dieter M. M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19830660119

Acetylacetonatorhodiumolefin systems, allylrhodium complexes, or (Ph3P)3RhCl catalyzed the conversion of alkenes and molecular oxygen to carbonyl compounds via C=C-bond cleavage.For example, 2,3-dimethyl-2-butene was transformed into acetone.Butadiene and isoprene also undergo oxidative C=C-bond cleavage to form acrylaldehyde and related compounds.

Full text of DOI:10.1002/hlca.19830660119

Products guided by the article

Product name:3-Cyclohexene-1-carboxaldehyde

Cas No:100-50-5

R&D Labs maybe for 100-50-5

Shanghai Run-Biotech Co., Ltd.

website:http://www.run-biotech.com

Contact:+86-21-31576854/57171705 / 57171706

Address:second floor, building 3, No.999, jiangyue Road, minghang District, Shanghai, China
henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China
Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan
Hangzhou Neway Chemicals Co., Ltd.

Contact:+86-571-85095566

Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
Shanghai Synmedia Chemical Co., Ltd

Contact:+86-21-38681880

Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China

Relevant to this article

Synthesis and in vitro antimicrobial, antioxidant, and antiproliferative activities of some new pyrano[2,3-c]pyrazoles containing 1,2-azaphospholes, 1,3,2-diazaphosphinines and phosphonate moieties

Doi:10.1080/00397911.2021.1939059
(2021)
Isolation and characterization of seven lyso platelet-activating factors and two lyso phosphatidylcholines from the crude drug 'Suitetsu' (the leech, Hirudo nipponica)

Doi:10.1248/cpb.41.1366
(1993)
Antioxidant activity of new aramide nanoparticles containing redox-active N-phthaloyl valine moieties in the hepatic cytochrome P₄₅₀ system in male rats

Doi:10.3390/molecules17078255
(2012)
Doi:10.1016/S0040-4039(01)89632-5
(1967)
Determination of phosphoric acid mono- and diesters in municipal wastewater by solid-phase extraction and ion-pair liquid chromatography-tandem mass spectrometry

Doi:10.1021/ac0517186
(2006)
Direct Access to 2,3,4,6-Tetrasubstituted Tetrahydro-2H-pyrans via Tandem S_N2′-Prins Cyclization

Doi:10.1021/acs.orglett.7b02270
(2017)

Article Doi