Helvetica Chimica Acta p. 177 - 185 (1983)
Update date:2022-08-11
Topics:
Boennemann, Helmut
Nunez, Washington
Rohe, Dieter M. M.
Acetylacetonatorhodiumolefin systems, allylrhodium complexes, or (Ph3P)3RhCl catalyzed the conversion of alkenes and molecular oxygen to carbonyl compounds via C=C-bond cleavage.For example, 2,3-dimethyl-2-butene was transformed into acetone.Butadiene and isoprene also undergo oxidative C=C-bond cleavage to form acrylaldehyde and related compounds.
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Doi:10.1080/00397911.2021.1939059
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