Tetrahedron p. 2165 - 2172 (1981)
Update date:2022-08-30
Topics:
Boyer, J.
Corriu, R. J. P.
Perz, R.
Reye, C.
The reduction of carbonyl compounds carried out with ethoxyhydrogenosilanes and alkali metal fluorides as catalysts and without solvent is highly selective.The reactivity order is aldehyde> ketone> ester.The reduction of aldehydes is possible in the presence of ketones, and of ketones in the presence of esters.The keto-group in a keto-ester can be selectively reduced.The high selectivity of this system is due to three factors: hydrogenosilane reactivity (EtO)2SiMeH <(EtO)3SiH, nature of the salt (KF
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(2021)
