First general synthesis of monosilyl acetals. Trimethylsilyl trapping of the intermediate in DIBALH reduction of carboxylic acid esters using trimethylsilyl trifluoromethanesulfonate

DOI: 10.1016/S0040-4039(00)60326-X

Source and publish data:

Tetrahedron Letters p. 1491 - 1494 (1993)

Update date:2022-08-17

Topics:

Authors:

Kiyooka, Syun-Ichi

Shirouchi, Masashi

Kaneko, Yuichi

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Article abstract of DOI:10.1016/S0040-4039(00)60326-X

The intermediate generated by the DIBALH reduction of carboxylic acid esters reacts with trimethylsilyl trifluoromethanesulfonate (TMSOTf) in the presence of pyridine to afford the corresponding monosilyl acetals in good yields.

Full text of DOI:10.1016/S0040-4039(00)60326-X

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