EPOXIDATION OF 2,3-DIMETHYL-2-BUTENE BY SUBSTITUTED BENZYLAZOBENZENE α-HYDROPEROXIDES IN C6D6

DOI: 10.1016/S0040-4039(00)81345-3

Source and publish data:

Tetrahedron Letters p. 123 - 126 (1983)

Update date:2022-08-16

Topics:

Authors:

Baumstark, A. L.

Vasquez, P. C.

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Article abstract of DOI:10.1016/S0040-4039(00)81345-3

The reaction of substituted benzylazobenzene α-hydroperoxides, 2a-f, with 2,3-dimethyl-2-butene in C6D6 at 34 deg produced tetramethyloxirane in 90percent yield; was of the first order in ROOH and in alkene; and exhibited an excellent LFER vs. sigma values (ρ=1.1 +/- 0.1).

Full text of DOI:10.1016/S0040-4039(00)81345-3

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