Journal of the Chemical Society. Chemical communications p. 2183 - 2184 (1995)
Update date:2022-08-16
Topics:
Griffith, William P.
Parkin, Bernardeta C.
White, Andrew J. P.
Williams, David J.
The crystal structure of the title compound, 1, reveals the presence of two distinct types of tungsten atom in which the four bearing peroxo groups have distorted pentagonal-bipyramidal geometries and the remaining two are octahedral; 1 is an effective catalyst for monoalkene epoxidation, and the oxidation of primary and secondary alcohols, with H2O2 as co-oxidant.
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