The first calibration of an aminiumyl radical ion clock: Why N-cyclopropylanilines may be poor mechanistic probes for single electron transfer

Article abstract of DOI:10.1039/b702157g

Using direct and indirect electrochemical methods, the rate constant for ring opening of the radical cation generated from N-cyclopropyl-N-methylaniline was found to be 4.1 × 10⁴ s^-1. The Royal Society of Chemistry.