Stereoselective reactions. 29. Lithium-hydrogen interchange between achiral tridentate lithium amides and chiral bidentate amines. An approach to catalytic enantioselective

DOI: 10.1016/S0040-4020(97)10144-2

Source and publish data:

Tetrahedron p. 16987 - 16998 (1997)

Update date:2022-08-15

Topics:

Authors:

Yamashita, Toyoharu

Sato, Daisaku

Kiyoto, Taro

Kumar, Arvind

Koga, Kenji

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Article abstract of DOI:10.1016/S0040-4020(97)10144-2

¹H-NMR spectral studies have shown that lithium-hydrogen interchange between a chiral bidentate amine ((R)-3b) and an achiral tridentate lithium amide (5a) occurs rapidly in THF, favoring the exclusive formation of a chiral bidentate lithium am

Full text of DOI:10.1016/S0040-4020(97)10144-2

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