THE NUCLEOPHILIC AROMATIC PHOTOSUBSTITUTION IN PHOTOAFFINITY LABELLING. A MODEL STUDY OF A CYCLOHEXIMIDE DERIVATIVE.

DOI: 10.1016/S0040-4039(00)94861-5

Source and publish data:

Tetrahedron Letters p. 2489 - 2492 (1985)

Update date:2022-08-11

Topics:

Authors:

Castello, A.

Marquet, J.

Moreno-Manas, M.

Sirera, X.

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Article abstract of DOI:10.1016/S0040-4039(00)94861-5

The photoreactions of several 4-nitrocatechol ethers with the relatively hard nucleophile methylamine occurs at the meta position respect to the nitro group.A derivative of the antibiotic cycloheximide carrying a 4-nitrocatechol ether moiety reacts with methylamine affording an in vitro model for photoaffinity labelling.

Full text of DOI:10.1016/S0040-4039(00)94861-5

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