
Journal of the Chemical Society. Chemical communications p. 309 - 310 (1980)
Update date:2022-08-29
Topics:
Kresge, A. J.
Tang, Y. C.
A new spectroscopic technique for measuring the rate of nitramide decomposition revealed a second pathway for this reaction and allowed extension of the Broensted relation for the first (traditional) pathway into more basic regions where the onset of relatively sharp curvature was detected; these results suggest a mechanism for the first reaction pathway in which proton transfer is not concerted with heavy atom reorganization.
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