Synthesis of Hexahydroindenones through a Diels-Alder Cycloaddition and Nazarov Cyclization Sequence of Triene Alcohols

DOI: 10.1246/bcsj.60.325

Source and publish data:

Bulletin of the Chemical Society of Japan p. 325 - 334 (1987)

Update date:2022-08-30

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Authors:

Wada, Eiji

Fujiwara, Isamu

Kanemasa, Shuji

Tsuge, Otohiko

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Article abstract of DOI:10.1246/bcsj.60.325

The Diels-Alder cycloaddition of 4-methylene-1,5-hexadien-3-ols with olefinic dienophiles such as dimethyl maleate, fumarate, and N-methylmaleimide produces 1-(1-cyclohexenyl)-2-propen-1-ols.These diene alcohols are oxidized with activated manganese(IV) o

Full text of DOI:10.1246/bcsj.60.325

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