Palladium(II)-Catalyzed Cyclopropanation of Simple Allyloxy and Allylamino Compounds and of 1-Oxy-1,3-butadienes with Diazomethane

DOI: 10.1055/s-1990-26844

Source and publish data:

Synthesis p. 246 - 248 (1990)

Update date:2022-08-11

Topics:

Authors:

Tomilov, Yu. V.

Kostitsyn, A. B.

Shulishov, E. V.

Nefedov, O. M.

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Article abstract of DOI:10.1055/s-1990-26844

(Alkyloxymethyl)-, (aminomethyl)-, (2-alkoxyethenyl)-, (2-acetoxyethenyl)-, and (2-siloxyethenyl)cyclopropanes are obtained in high yields by reaction of allyl alcohol or derivatives, allylamines, 1-alkoxy-, 1-acetoxy-, and 1-trimethylsiloxy-1,3-butadienes with diazomethane in dichloromethane/diethylether in the presence of bis(benzonitrile)palladium dichloride.

Full text of DOI:10.1055/s-1990-26844

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