Palladium(II)-Catalyzed Cyclopropanation of Simple Allyloxy and Allylamino Compounds and of 1-Oxy-1,3-butadienes with Diazomethane

DOI: 10.1055/s-1990-26844

Source and publish data:

Synthesis p. 246 - 248 (1990)

Update date:2022-08-11

Topics:

Authors:

Tomilov, Yu. V.

Kostitsyn, A. B.

Shulishov, E. V.

Nefedov, O. M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1990-26844

(Alkyloxymethyl)-, (aminomethyl)-, (2-alkoxyethenyl)-, (2-acetoxyethenyl)-, and (2-siloxyethenyl)cyclopropanes are obtained in high yields by reaction of allyl alcohol or derivatives, allylamines, 1-alkoxy-, 1-acetoxy-, and 1-trimethylsiloxy-1,3-butadienes with diazomethane in dichloromethane/diethylether in the presence of bis(benzonitrile)palladium dichloride.

Full text of DOI:10.1055/s-1990-26844

Products guided by the article

Product name:Methyl(cyclopropylmethyl) ether

Cas No:1003-13-0

R&D Labs maybe for 1003-13-0

Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
zonk drug r&d limited

Contact:+86-20-32051076

Address:1105,Building A, International Business Incubator,Science City
HAORUI ENTERPRISES LLC

Contact:(1) 206-3550089

Address:5115 NE 8TH PL, Renton, WA 98059 USA
Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China

Relevant to this article

A simple and eco-friendly process catalyzed by montmorillonite K-10, with air as oxidant, for synthesis of 2-substituted benzothiazoles

Doi:10.1007/s11164-014-1619-4
(2015)
Hierarchically porous nanostructures through phosphonate-metal alkoxide condensation and growth using functionalized dendrimeric building blocks

Doi:10.1039/c1cc12310f
(2011)
Computationally-Led Ligand Modification using Interplay between Theory and Experiments: Highly Active Chiral Rhodium Catalyst Controlled by Electronic Effects and CH–π Interactions

Doi:10.1002/adsc.201701191
(2018)
Stereoselective Cycloaddition of Pyridinium or Isoquinolinium Methylides with Olefinic Dipolarophiles and Subsequent Cycloadditions of the Cycloadducts with Nitrile Oxides

Doi:10.1246/bcsj.59.3631
(1986)
IR SPECTRAL STUDY OF THE VACUUM PYROLYSIS OF 2,3-DIMETHYL- AND 2,3,7,8-TETRAMETHYL-5-GERMASPIRO<4.4>NONA-2,7-DIENES AS POSSIBLE SOURCES OF 3,4-DIMETHYLCYCLOPENTENE-3-GERMYLENE

Doi:10.1007/BF00957184
()
Model Studies on Protease-Catalysed Peptide Synthesis Using 9-Fluorenylmethoxycarbonyl Protected Amino Acid Derivatives

Doi:10.1007/BF00810932
(1992)

Article Doi