DOI: 10.1039/C5GC01741F
Green Chemistry
ARTICLE
Journal Name
In this work, a simple and efficient catalyst combination 6. a) J. Mitra, X. Zhou and T. Rauchfuss, Green Chem., 2015, 17, 307;b)
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conversion of biomass derived 2,5-HD to DMTHF. Almost
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7
quantitative conversion of 2,5-HD to DMTHF could be fulfilled 7. R. J. Sullivan, E. Latifi, B. K. M. Chung, D. V. Soldatov and M. Schlaf,
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which was a milder condition than those reported for this 8. L. J. Xu, Y. Y. Jiang, Q. Yao, Z. Han, Y. Zhang, Y. Fu, Q. X. Guo and
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system can be easily recovered and reused for at least five times 9. a) Q. N. Xia, Q. Cuan, X. H. Liu, X. Q. Gong, G. Z. Lu and Y. Q.
4
without decreasing the activity and selectivity. In the reaction
process, the reactant (2,5-HD) is first converted into the
intermediate 2,5-HDO by hydrogenation, which is further
Wang, Angew. Chem. Int. Ed., 2014, 53, 9755;b) M. Mascal, S. Dutta
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promote the reaction cooperatively. We believe that the highly
efficient, greener, facilely prepared, and easily recoverable
catalytic system has great potential application for the reaction.
Acknowledgements
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The authors thank the National Natural Science Foundation of
China and Chinese Academy of Sciences for financial support.
This work was supported by National Natural Science
Foundation of China (21003133, 21321063), and Chinese
Academy of Sciences (KJCX2.YW.H30).
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aBeijing National Laboratory for Molecular Sciences, Institute of
Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
bChemical Engineering College, Inner Mongolia University of
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