
Tetrahedron p. 1871 - 1873 (1981)
Update date:2022-08-16
Topics:
Yamamoto, Jiro
Imagawa, Masahiro
Yamauchi, Sigeyuki
Nakazava, Osamu
Umezu, Masahiro
et al.
Mixing with equimolar solutions of pyridine N-oxide or its homologs and SbCl5 in CCl4 deposited 1:1 complexes as colorless crystals in high yield.On thermolysis, these complexes underwent intramolecular oxygen transfer to give selectively the corresponding 2-pyridone derivatives.N,N-Dimethylaniline N-oxide and SbCl5 also gave a crystalline 1:1 complex which on termolysis yield o-dimethylaminophenol in good yield.
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