Electrostatic interaction and induced fitting of the rhodium(I) complex coordinated by diphosphine ligand having an amino group in the diastereoselective hydrogenation of dehydrodipeptides

DOI: 10.1016/S0022-328X(97)00076-4

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Journal of Organometallic Chemistry p. 115 - 120 (1997)

Update date:2022-08-17

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Authors:

Yamada, Issaku

Fukui, Kouta

Aoki, Yoshihiro

Ikeda, Satoru

Yamaguchi, Motowo

Yamagishi, Takamichi

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Article abstract of DOI:10.1016/S0022-328X(97)00076-4

Rhodium(I)-[2-[2-(dimethylamino)ethyl]-1,3-propanediyl]bis(diphenylphosphine) (DPP-AE) catalyst achieved an effective 1,4-asymmetric induction and afforded high diastereoselectivity (max. 96% d.e.) in the hydrogenation of dehydrodipeptides in protic solve

Full text of DOI:10.1016/S0022-328X(97)00076-4

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