Journal of the Chemical Society, Dalton Transactions p. 5 - 8 (1987)
Update date:2022-08-11
Topics:
Constable, Edwin C.
Holmes, Jeremy M.
McQueen, Roderick C. S.
The preparation of a simple unsubstituted quinquedentate macrocycle incorporating a 2,2':6',2"-terpyridine moiety by a transient template reaction is described.The cobalt(II), nickel(II), copper(II), and zinc(II) complexes of the ligand are described, as is the oxidation-reduction chemistry of these compounds.E.s.r. studies indicate that pentagonal-bipyramidal complexes, with solvent molecules occupying the axial sites, are formed.
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