Tetrahedron Letters p. 3915 - 3918 (1980)
Update date:2022-08-10
Topics:
Hayashi, Tamio
Katsuro, Yoshio
Kumada, Makoto
The substitution of the siloxy group in silyl enol ethers with Grignard reagents to form olefins is accomplished by use of nickel acetylacetonate or phosphine-nickel complexes as catalysts, the stereo- and regiochemistry of coupled olefins depending upon the nature of the catalyst and reaction conditions employed.
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