Journal of the Chemical Society. Chemical communications p. 452 - 453 (1985)
Update date:2022-08-18
Topics:
Hwu, Jih Ru
Mechanistic studies of the reaction between α-cyclopropylbenzyl alcohol and methyl-lithium followed by hexamethyldisilane indicate that disproportionation of intermediate (4) with trimethylsilyl anion as catalyst provides cyclopropyl phenyl ketone; in situ 1,4-addition of trimethylsilyl anion to the latter compound leads to the major product, γ-trimethylsilylbutyrophenone (2).
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Doi:10.1021/jm00226a002
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