A sliding cyclohexane rearrangement mediated by zirconium tetrachloride

DOI: 10.1016/0040-4039(96)00634-X

Source and publish data:

Tetrahedron Letters p. 3607 - 3608 (1996)

Update date:2022-08-16

Topics:

Authors:

Harrowven, David C.

Dainty, Richard F.

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Article abstract of DOI:10.1016/0040-4039(96)00634-X

6-Methoxytetralins may be smoothly transformed into 5-methoxytetralins through the action of zirconium tetrachloride. The rearrangement occurs at ambient temperature in chloroform and proceeds via fragmentation of the carbon-carbon bond para to the methoxy substituent followed by an intramolecular Friedel-Crafts alkylation.

Full text of DOI:10.1016/0040-4039(96)00634-X

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