Tetrahedron Letters p. 8427 - 8430 (1993)
Update date:2022-08-11
Topics:
Adam, Waldemar
Prechtl, Frank
Richter, Markus J.
Smerz, Alexander K.
Epoxidation of allylic alcohols with dimethyldioxirane is accompanied by oxidation of the hydroxy functionality; thus enone formation increases with decreasing substitution at the C-C double bond; nonetheless, selective epoxidation can be obtained by acylation of the alcohol functionality.
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